The short answer is "probably not".

Long answer:

If you look into it (as a private pilot, you should know "how" already), you will most likely find that there will be a number of obstacles in your path at the majority of large airports.

These obstacles can include (but are not limited to) :
- Airspace restrictions (both local area and at the airport itself) so, for example, you might need IR rating and a suitably equipped aircraft.
- Technical limitations for your aircraft (e.g. your aircraft might not be able to meet speed requirements)
- Airport prohibitions, for example Heathrow publish the following:

> Flights for recreational, commemorative, charity and record breaking
> purposes, light twin engined private aircraft and all light single
> engined aircraft will not be permitted to use the airport. 'Light
> aircraft' shall be defined as any aircraft that has a maximum gross
> take-off weight of 12,500 lb (5,670 KG) or less.

And even if the immediate technical obstacles don't apply, you might find commercial obstacles such as (but not limited to) :
- The requirement to nominate and use a handling agent for ground ops
- Very high landing fees