Aside from Van’s planes, are there any planes capable of both XC and Aerobatics?
The Cessna 152 Aerobat is certified for aerobatics and also has passible XC performance (depending on what you want to optimize). You can fit two statistically small people and a bag with 100Kts cruise which gets you around a bit faster than a car depending on headwinds. Its also a widely produced airframe, easy to get parts and A&P's for.
There is apparently an aerobatic Bonanza out there which could be a decent candidate but you would need to actually find one.
Bob Hoover made it clear you can fly some aerobatic maneuvers in a Shrike Commander which is a decent sized twin for getting places.