Yes, there is.
Since ejecting from an aircraft destroys the aircraft, you'll just have to buy one with an ejection seat. I'd recommend an L-39 or a Dassault Alpha Jet. They can be had for about \$1.5-$4 million.
After that you can pretty much do whatever you want. Head out over the ocean, pull the ejector handle, wait for the Coast Guard.
Seriously though, no. The chances of serious injury or death, especially for somebody who does not have the years physical training required of fighter pilots is almost sure to result in your own permanent injury or death. Ejecting from an aircraft destroys the aircraft, so nobody is offering a "fly and eject" experience package. Might as well take the "Russian Roulette" experience with it, you're chances are probably better with that game.