It's not just big twins that have "high compression" or use turbos. Many four and six seat engines have higher compression engines also without turbos. My Lycoming O-360-A1F6D has no turbo. has 8.5:1 compression ratio cylinders and needs 100LL to prevent early detonation.
https://www.lycoming.com/sites/default/files/O-HO-IO-HIO-AIO%20%26%20TIO-360%20Oper%20Manual%2060297-12.pdf
O-360-A series
FAA Type Certificate ...................................... 286
Rated horsepower ......................................... 180
Rated speed, RPM.......................................... 2700
Bore, inches.................................................... 5.125
Stroke, inches.................................................. 4.375
Displacement, cubic inches............................. 361.0
Compression ratio .......................................... 8.5:1
(The -A1F6D indicates things like hollow shaft for oil pressure to drive the constant speed propeller via governor, counterweights on the crankcase to balance the cylinders, dual magneto vs 2 separate magnetos).
And if you look at page pdf page 42 (marked as 3-10), almost all the O-360 engines need higher octane fuel:
FUEL AND OIL *Aviation Grade Fuel
Model Series Minimum Grade
O-360-B, -D 80/87
O-360-A1P, -C1F, -C4F; HO-360-C1A 91/96
O-360-C, -F; HO-360-A, -B; IO-360-B, -E; HIO-360-B 91/96 or 100/130
O-360-J2A 91/96 or 100/100LL
IO-360-L2A, -M1A, -M1B 91/96 or 100LL
HIO-360-G1A 91/96 or 100LL
O-360-A, -C1G, -C4P, -A1H6; TIO-360-C1A6D 100/100LL
IO-360-B1G6, -C1G6, -J, -K2A, -A1D6D, -A3B6, -A3D6D;
HIO-360-A1B 100/100LL
AIO-360-A, -B; IO-360-A, -C, -D, -F 100/130
HIO-360-A, -C, -D, -E, -F 100/130
TIO-360-A 100/130
The fuel injected version used in the retractable gear version of my plane. IO-360Axxx, has higher ratio cylinders, 8.7:1 and develops 15-20 more horsepower.
Here's a little more info on Leaded Aviation fuel, from https://www.faa.gov/about/initiatives/avgas/
FAA Home ▸ About FAA ▸ Programs & Initiatives ▸ Aviation Gasoline
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The Federal Aviation Administration (FAA) shares the Environmental Protection Agency's (EPA) concerns about lead emissions from small aircraft. Owners and operators of more than 167,000 piston-engine aircraft operating in the United States rely on aviation gasoline (avgas) to power their aircraft. Avgas is the only remaining lead-containing transportation fuel. Lead in avgas prevents damaging engine knock, or detonation, that can result in a sudden engine failure. Lead is a toxic substance that can be inhaled or absorbed in the bloodstream, and the FAA and EPA and industry are partnering to remove it from avgas. Avgas emissions have become the largest contributor to the relatively low levels of lead emissions produced in this country.
To help "get the lead out," FAA is supporting the research of alternate fuels at our William J. Hughes Technical Center in Atlantic City. We are working with the aircraft and engine manufacturers, fuel producers, the EPA and industry associations to overcome technical and logistical challenges to developing and deploying a new, unleaded fuel.
The FAA continues to work with EPA to make this a smooth transition and to ensure the supply of aviation gasoline is not interrupted, and that all aircraft can continue to fly.
This follow-up article has more info:
The unleaded fuel disaster - what it means for pilots | Air Facts Journal
https://airfactsjournal.com/2018/11/the-unleaded-fuel-disaster-what-it-means-for-pilots/
The new timeline focuses on testing of an unleaded fuel being developed by Shell—now the lone participant in PAFI following the elimination of Swift Fuels’ candidate fuel.
Another article, from AOPA https://www.aopa.org/news-and-media/all-news/2018/october/03/faa-sees-mid-2020-completion-of-unleaded-avgas-project
The FAA had halted testing last spring, calling for Shell and Swift to address concerns that emerged in data gathered in early phase tests.
In August, following a meeting of the PAFI Steering Group at AOPA Headquarters, AOPA reported on PAFI’s continued progress and plans going forward.
Before flight testing under PAFI resumes, preliminary work “will include clearing material compatibility, durability, detonation, and performance issues,” the FAA said.
Addressing the extension of testing into 2020, the FAA reiterated that “the PAFI mission endures,” noting, “although it will take additional time to realize this goal, it is essential to ensure a viable, safe, and economical fuel is ultimately authorized.”
“AOPA is encouraged to see Shell’s continued commitment and efforts to work on issues and come up with mitigations,” said David Oord, AOPA senior director of regulatory affairs. “We and the other members of the PAFI steering group were pleased to see that early results from their efforts look promising.”
Oord reiterated continued support of the government-industry efforts to identify, test, and authorize a general aviation fleetwide unleaded replacement for 100LL avgas, noting AOPA’s longstanding position that the resulting fuel must not require extensive changes to engines, aircraft systems, or fuel delivery systems.
“Ultimately, we are looking for the best fuel, whether it results from PAFI or other means.The goal is the same, regardless of the path we take to get there.”
I recall seeing a (or some) articles during the Feb 2019 Gov't shutdown saying testing was suspended for an unknown time, so unleaded fuel will not be available for a while.
The higher horse power engines, like the O-540 and IO-540, are 6-cylinder versions of my 4 cylinder engine. So if mine has 180HP/4 cylinders, ~ 45 HP/cylinder, than an O-540 is generating ~ 6x45 = 270HP, and and IO-540 ~ 50 HP/cyl = 300 HP. Those can be found on 6-seat planes, and the bigger twins. We all have the same need for 100LL fuel. My home airport has stopped carrying 87 octave mogas, I presume that demand has dropped, and only carries 100 LL now. I can't even recall the last airport I was at that had 87 mogas.