Assuming that you have a single-engine land certificate, you can log PIC time if, per §91.109
(c) No person may operate a civil aircraft in simulated instrument
flight unless—
(1) The other control seat is occupied by a safety pilot who possesses
at least:
(i) A private pilot certificate with category and class ratings
appropriate to the aircraft being flown; or
You do not have to have endorsements for the particular aircraft e.g. high performance, or complex as long as you are rated in the category and class. FAA Legal Interpretation Herman - Logging PIC (2009)
Although these endorsements are required before a pilot may act as a
PIC of a high-performance and/or complex airplane, they are not
required to log PIC time if the pilot is rated for and is the sole
manipulator of the controls of the aircraft.
You may not log SIC time since the aircraft type does not require a second pilot. FAA Legal Interpretation Beaty - (2013) SIC Safety Pilot
Because the aircraft is type certificated for a single pilot, and
because the operation does not require a designated SIC (e.g. an
operation conducted under 14 c.P.R. § 135.101 which requires an SIC
under IFR), Pilot B is a safety pilot and not an SIC.
You may log SIC time, though I don’t know why you would want to. Legal Interpretation louis glenn - (2009)
When a pilot is operating an aircraft in simulated instrument flight,
14 C.F.R. § 91.109(b), in relevant part, requires that a safety pilot,
who possesses at least a private pilot certificate with category and
class ratings appropriate to the aircraft, occupy the other control
seat. Accordingly, Pilot B may log SIC time for the portion of the
flight during which Pilot B acts as safety pilot because Pilot B was a
required flight crewmember for that portion of the flight under § 91.1
09(b). The FAA previously has interpreted that a person acting as
safety pilot for a portion of a flight may not log cross-country time
because that person is not a required flight crewmember for the entire
flight.
You may not log cross-country time since you haven’t taken off and landed. FAA Legal Interpretation Gebhart - (2009) Safety Pilot
In your example, Pilot A may log the entire flight (2.2 hours) of PIC
flight time because that pilot was the sole manipulator of the
controls for the entire flight. Pilot B may log the portion of the
flight during which Pilot A operated in simulated instrument flight
and Pilot B acted as the safety pilot (2.0 hours) because Pilot B was
a required flight crewmember for that portion of the flight under 14
C.F.R. § 91.109(b).